Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 24, Pages 9902-9905Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja3036459
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Funding
- Chinese Academy of Sciences
- National Natural Science Foundation of China [21172226, 21133011]
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A new strategy for generating benzylpalladium reactive species from toluenes via nondirected C(sp(3))-H activation has been developed. This led to construction of an efficient Pd-catalyzed reaction protocol for the oxidative carboxylation of benzylic C-H bonds to form substituted 2-phenylacetic acid esters and derivatives from inexpensive, commercially available starting materials.
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