4.8 Article

C(sp)-C(sp3) Bond Formation through Cu-Catalyzed Cross-Coupling of N-Tosylhydrazones and Trialkylsilylethynes

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 13, Pages 5742-5745

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja3004792

Keywords

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Funding

  1. 973 Program [2009CB825300]
  2. RFDP
  3. NSFC

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Copper-catalyzed cross-coupling of N-tosylhydrazones with trialkylsilylethynes leads to the formation of C(sp)-C(sp(3)) bonds. Cu carbene migratory insertion is proposed to play the key role in this transformation.

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