Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 22, Pages 9046-9049Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja302071t
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- U.S. DOE Office of Nuclear Energy
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Krypton (Kr) and xenon (Xe) adsorption on two partially fluorinated metal organic frameworks (FMOFCu and FMOFZn) with different cavity size and topologies are reported. FMOFCu shows an inversion in sorption selectivity toward Kr at temperatures below 0 degrees C while FMOFZn does not. The 1D microtubes packed along the (101) direction connected through small bottleneck windows in FMOFCu appear to be the reason for this peculiar behavior. The FMOFCu shows an estimated Kr/Xe selectivity of 36 at 0.1 bar and 203 K.
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