4.8 Article

Enantiopure C1-Symmetric Bis(imino)pyridine Cobalt Complexes for Asymmetric Alkene Hydrogenation

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 10, Pages 4561-4564

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja300503k

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Funding

  1. Natural Sciences and Engineering Research Council of Canada
  2. US-UK Fulbright Commission
  3. AstraZeneca
  4. Direct For Mathematical & Physical Scien
  5. Division Of Chemistry [1026084] Funding Source: National Science Foundation

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Enantiopure C-1-symmetric bis(imino)pyridine cobalt chloride, methyl, hydride, and cyclometalated complexes have been synthesized and characterized. These complexes are active as catalysts for the enantioselective hydrogenation of geminal-disubstituted olefins.

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