Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 37, Pages 15165-15168Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja307670k
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Funding
- Spanish Government [CTQ-2009-12168]
- CAM [CS2009/PPQ-1634]
- Consejo Nacional de Ciencia y Tecnologia de Mexico
- MICINN
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The first copper-catalyzed formal carboboration of alkynes, in which a C-B bond and a C-C bond are created in a single catalytic cycle, is presented. The reaction proceeds with high regioselectivity and syn-stereoselectivity to form tri- and tetrasubstituted vinylboronic esters from commercially available bis-(pinacolato)diboron. A subsequent cross-coupling reaction gives access to highly substituted alkenes.
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