4.8 Article

Correlation of π-Conjugated Oligomer Structure with Film Morphology and Organic Solar Cell Performance

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 27, Pages 11064-11067

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja302320c

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Funding

  1. DFG
  2. BMBF [OPEG 13N9720, OPA 13N98872]

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The novel methyl-substituted dicyanovinyl-capped quinquethiophenes 1-3 led to highly efficient organic solar cells with power conversion efficiencies of 4.8-6.9%. X-ray analysis of single crystals and evaporated neat and blend films gave insights into the packing and morphological behavior of the novel compounds that rationalized their improved photovoltaic performance.

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