Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 38, Pages 15728-15731Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja307995f
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- NSERC of Canada
- Canada Research Chair
- OGS Scholarship
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The readily prepared borenium salt [(IiPr(2))(BC8H14)][B(C6F5)(4)] (2) [IiPr(2) = C3H2(NiPr)(2)] is shown to activate H-2 heterolytically in the presence of tBu(3)P. Compound 2 also acts as a catalyst for the metal-free hydrogenation of imines and enamines at room temperature.
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