Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 48, Pages 19600-19603Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja310372f
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Funding
- PRESTO Program of JST
- Ministry of Education, Culture, Sports, Science and Technology (MEXT) of Japan [23685020]
- NEXT Program of the Japan Society for the Promotion of Science (JSPS)
- Asahi Glass Foundation
- Grants-in-Aid for Scientific Research [23685020, 11J03688] Funding Source: KAKEN
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Azaboradibenzo[6]helicene, a new semiconductor material possessing helical chirality, has been synthesized via a tandem bora-Friedel Crafts-type reaction. Unprecedented carrier inversion between the racemate (displaying p-type semiconductivity) and the single enantiomer (displaying n-type semiconductivity) was observed and can be explained by changes in the molecular packing induced by helical homochirality.
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