Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 45, Pages 18577-18580Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja309635w
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Funding
- University of North Carolina at Chapel Hill
- National Institute of General Medical Sciences [R01 GM098340]
- Eli Lilly New Faculty Award
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A direct intramolecular anti-Markovnikov hydroetherification reaction of alkenols is described. By employing Catalytic quantities of commercially available 9-mesityl-10-methylacridinium perchlorate and 2-phenyl-malononitrile as a redox-cycling source of a H-atom, we report the anti-Markovnikov hydroetherification of alkenes with complete regioselectivity, In addition, we present results demonstrating that this novel catalytic system can be applied to the anti-Markovnikov hydrolactonization of alkenoic acids.
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