Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 43, Pages 17881-17884Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja308801n
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Funding
- 973 Program [2012CB821705, 2011CB932504]
- National Natural Science Foundation of China [21073191, 21103189, 21221001]
- Natural Science Foundation of Fujian Province [2011J06005]
- Chinese Academy of Sciences [XDA07070200]
- U.S. National Science Foundation [DMR-0846958]
- Division Of Materials Research
- Direct For Mathematical & Physical Scien [0846958] Funding Source: National Science Foundation
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From a basic tetrahedral Cu4I4 cluster, a new MTN-type cluster-organic framework (COZ-1) containing giant 6(4)5(12) and 5(12) cages was successfully constructed. The 6(4)5(12) cage has an inner diameter of 2.6 nm and a large pore volume of 9.2 nm(3); these tetrahedral Cu4I4 clusters with bulky size offer new opportunities for not only the formation of 4-connected zeotype structures but also the integration of porosity and photoluminescent properties from both the cluster and the framework.
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