4.8 Article

Field Effects Induce Bathochromic Shifts in Xanthene Dyes

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 25, Pages 10502-10508

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja302445w

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Funding

  1. National Institutes of Health [RO1 EB002044]
  2. NSF [0741993]

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There is ongoing interest in near-infrared (NIR) absorbing and emitting dyes for a variety of biomedical and materials applications. Simple and efficient synthetic procedures enable the judicious tuning of through-space polar (field) effects as well as low barrier hydrogen bonding to modulate the HOMO-LUMO gap in xanthene dyes. This affords unique NIR-absorbing xanthene chromophores.

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