Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 29, Pages 11940-11943Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja305196u
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Funding
- European Research Council
- Oppenheimer Fund
- EPSRC
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A 3D hybrid zinc formate framework, [NH4][Zn(HCOO)(3)], possessing an acs topology, shows a high degree of mechanical anisotropy and negative linear compressibility (NLC) along its c axis. High-pressure single-crystal X-ray diffraction studies and density functional theory calculations indicate that contraction of the Zn-O bonds and tilting of the formate ligands with increasing pressure induce changes in structure that result in shrinkage of the a and b axes and the NLC effect along c.
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