Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 50, Pages 20276-20278Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja310386m
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- Fonds der Chemischen Industrie
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A highly enantioselective polycyclization method has been developed using the combination of Lewis acid activation with iridium-catalyzed allylic substitution. This strategy relies on direct use of branched, racemic allylic alcohols and furnishes a diverse and unique set of carbo- and heteropolycyclic ring systems in good yields and >= 99% ee.
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