Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 36, Pages 14982-14990Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja305163t
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Funding
- EU
- Spanish MINECO [MAT2011-61584, MAT2009-13977-C0, MAT2007-61584, CTQ2008-06720]
- CONSOLIDER project on Molecular Nanoscience [CSD-2007-00010]
- Generalidad Valenciana
- Gobierno de Aragon (Project MOL-CHIP)
- Spanish MECD
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A robust, stable and processable family of mononuclear lanthanoid complexes based on polyoxometalates (POMs) that exhibit single-molecule magnetic behavior is described here. Preyssler polyanions of general formula [LnP(5)W(30)O(110)](12-) (Ln(3+) = Tb, Dy, Ho, Er, Tm, and Yb) have been characterized with static and dynamic magnetic measurements and heat capacity experiments. For the Dy and Ho derivatives, slow relaxation of the magnetization has been found. A simple interpretation of these properties is achieved by using crystal field theory.
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