4.8 Article

High-Yielding, Versatile, and Practical [Rh(III)Cp*]-Catalyzed Ortho Bromination and Iodination of Arenes

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 20, Pages 8298-8301

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja302631j

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Funding

  1. DFG (IRTG Munster-Nagoya)
  2. European Research Council under the European Community [25936]

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We report a uniquely high-yielding, general, and practical ortho bromination and iodination reaction of different classes of aromatic compounds. This reaction occurs by Rh(III)-catalyzed C-H bond activation methodology and is therefore the first example of the application of this cationic catalyst for C-Br and C-I bond formation.

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