Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 46, Pages 18924-18927Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja3089907
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Funding
- National Basic Research Program of China (973 Program) [2009CB825300]
- National Science Foundation of China [21172006]
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A novel and efficient copper-catalyzed azidation reaction of anilines via C-H activation has been developed. This method, in which the primary amine acts as a directing group by coordinating to the metal center, provides ortho azidation products regioselectively under mild conditions. This effective route for the synthesis of aryl azides is of great significance in view of the versatile reactivity of the azide products.
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