Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 7, Pages 3338-3341Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja211770y
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Funding
- Funding Program for Next Generation World-Leading Researchers [GR025]
- JSPS
- Grants-in-Aid for Scientific Research [24105505, 11J09130] Funding Source: KAKEN
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Synthetic use of alpha-aminoalkyl radicals formed by single electron oxidation of amines is quite limited. Here we demonstrate addition of alpha-aminoalkyl radicals to electron-deficient alkenes by visible-light-mediated electron transfer using transition metal polypyridyl complexes as photocatalysts, via a sequential redox pathway.
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