Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 42, Pages 17436-17439Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja3082523
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Funding
- Non-Equilibrium Energy Research Center
- U.S. Department of Energy, Offices of Basic Energy Sciences [DE-SC0000989]
- Defense Threat Reduction Agency [HDTRA1-10-1-0023, HDTRA1-09-1-0007]
- National Science Foundation
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An efficient synthetic route to an A1/A2-difunctionalized pillar[5]arene containing resolvable planar chirality has been developed and the arene employed as a strut in the synthesis of P5A-MOE-1, which has been demonstrated by X-ray powder diffraction analysis-supported by modeling-to be isoreticular with MOF-5. This metal-organic framework has an active domain that expresses good and selective uptake of neutral and positively charged electron-poor aromatic guests, which effect color changes of the cubic crystals from faint yellow to deep orange, arising from charge transfer between the guests and active domain of P5A-MOE-1.
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