Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 15, Pages 6548-6551Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja301705z
Keywords
-
Categories
Funding
- National Basic Research Program of China [2012CB821600, 2010CB126103]
- Special Fund for Agro-scientific Research in the Public Interest [201103007]
- National Key Technologies RD Program [2011BAE06B05]
- Shanghai Scientific Research Program [10XD1405200]
- National Natural Science Foundation of China [21032006]
- Shanghai Pujiang Program [11PJ1412200]
- SIOC
Ask authors/readers for more resources
A Cu-mediated ligandless aerobic fluoroalkylation of arylboronic acids under mild conditions is described for the first time. The reaction tolerates a wide range of functional groups, allowing for further transformation. Mechanistic studies suggest that [RfCu] is the active Cu species that forms the desired perfluoroalkylarenes and that [RfCu] is generated from [PhCu] by either an oxidative addition/reductive elimination mechanism or nucleophilic substitution via a halogen ate intermediate.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available