Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 4, Pages 2020-2023Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja211272v
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- National Institutes of Health [NIGMS 078383]
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Enantioselective copper-catalyzed cyclization of gamma-alkenylsulfonamides and a delta-alkenylsulfonamide in the presence of a range of vinyl arenes results in variously functionalized 2-substituted chiral nitrogen heterocycles via a formal alkene C-H functionalization process. Application of this reaction to the concise synthesis of a 5-HT7 receptor antagonist is demonstrated.
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