Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 135, Issue 1, Pages 86-89Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja311082u
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Funding
- National Basic Research Program of China (973 Program) [2009CB825300]
- National Natural Science Foundation of China [20923005, 21025209, 21002111, 21121062]
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Enantioselective Pd(II)-catalyzed direct coupling of aminomethylferrocene derivatives with boronic acids was realized. With commercially available Boc-L-Val-OH as a ligand, planar-chiral ferrocenes could be synthesized in yields of 14-81% with up to 99% ee under mild conditions.
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