Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 29, Pages 11932-11935Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja304818c
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Funding
- Ministry of Education, Culture, Sports, Science and Technology, Japan [23655056]
- Grants-in-Aid for Scientific Research [23655056, 23750063] Funding Source: KAKEN
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The first catalytic double hydrophosphination of alkynes was achieved by reaction with diarylphosphines in the presence of an iron catalyst. The double hydrophosphination proceeded regioselectively and effectively for various secondary arylphosphines and terminal alkynes to give 1,2-bisphosphinoethane derivatives.
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