4.8 Article

Catalytic Carbon-Carbon σ-Bond Hydrogenation with Water Catalyzed by Rhodium Porphyrins

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 28, Pages 11388-11391

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja3047415

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Funding

  1. Chinese University of Hon Kong

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The catalytic carbon carbon-cabon sigma-bond activation and hydrogenation of [2.2]paracyclophane with water in a neutral reaction medium is demonstrated. The hydrogen from water is transferred to the hydrocarbon to furnish hydrogen enrichment in good yields.

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