Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 40, Pages 16877-16881Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja307539w
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Funding
- German Bundesministerium fur Bildung und Forschung (BMBF) [02NUK012C]
- Deutsche Forschungsgemeinschaft (DFG) [SFB 583]
- FAU Erlangen-Nuremberg [CM1006]
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We recently reported the formation of a bridging carbonate complex [{(((ArO)-Ar-Ad)(3)N)U}(2)(mu-eta(1):kappa(2)-CO3)] via reductive cleavage of CO2, yielding mu-oxo bridged complex, followed by the insertion of another molecule of CO2. In a similar strategy, we were able to isolate and characterize a series of mixed carbonate complexes U-CO2E-U, U-CS2E-U, and even U-OC(S)Se-U, by reacting bridged chalcogenide complexes [{(((ArO)-Ar-Ad)(3)N)U}(2)(mu-E)] (E = S, Se) with CO2, CS2, and COS. These chalcogenido mixed-carbonate complexes represent the first of their kind.
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