Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 23, Pages 9537-9540Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja300015n
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Funding
- National Science Foundation [ECS-0335765]
- ANSER Center, an Energy Frontier Research Center
- U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-SC0001059]
- government of Thailand's Commission on Higher Education
- Yulchon Foundation in Korea
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A major loss mechanism in dye-sensitized solar cells (DSCs) is recombination at the TiO2/electrolyte interface. Here we report a method to reduce greatly this loss mechanism. We deposit insulating and transparent silica (SiO2) onto the open areas of a nanoparticulate TiO2 surface while avoiding any deposition of SiO2 over or under the organic dye molecules. The SiO2 coating covers the highly convoluted surface of the TiO2 conformally and with a uniform thickness throughout the thousands of layers of nanoparticles. DSCs incorporating these selective and self-aligned SiO2 layers achieved a 36% increase in relative efficiency versus control uncoated cells.
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