Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 39, Pages 16430-16433Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja307628w
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Funding
- National Institute of Health [CA103823]
- Terrie Brodeur Breast Cancer Foundation
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The first total synthesis of triantennary, fully sialylated N-glycan of complex type is described. Two strategies for installation of sialylated antennae are explored, and both approaches converge on a global glycosylation step that delivers the desired tetradecasaccharide in good yields.
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