Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 4, Pages 1934-1937Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja209800x
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Funding
- Department of Energy, Office of Basic Energy Sciences [DE-SC0002235]
- NSF [DMR-0846958]
- CSULB SCAC
- Direct For Mathematical & Physical Scien
- Division Of Materials Research [0846958] Funding Source: National Science Foundation
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A new class of zeolite-type porous materials in which 3D frameworks are covalently functionalized with crystallographically ordered pendant metal clusters have been synthesized. This work demonstrates a new paradigm for and the feasibility of functionalizing zeolite-type frameworks through the conversion of extraframework sites in mineral zeolites into part of the framework for occupation by dangling metal clusters in metal-organic frameworks.
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