Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 15, Pages 6524-6527Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja300171y
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Funding
- Ministere de la Recherche et de l'Enseignement Superieur
- Centre National de la Recherche Scientifique (CNRS)
- Institut Universitaire de France (IUF)
- Region Bretagne
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A synthetic route to planar P-modified polycylic aromatic hydrocarbons (PAHs) is described. The presence of a reactive sigma(3),lambda(3)-P moiety within the sp(2)-carbon scaffold allows the preparation of a new family of PAHs displaying tunable optical and redox properties. Their frontier molecular orbitals (MOs) are derived from the corresponding phosphole MOs and show extended conjugation with the entire pi framework. The coordination ability of the P center allows the coordination-driven assembly of two molecular PAHs onto a Au-I ion.
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