Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 5, Pages 2551-2554Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja2119892
Keywords
-
Categories
Funding
- BP
- EPSRC
- NSERC
- University of Huelva
Ask authors/readers for more resources
Photolytic ligand displacement and salt metathesis routes have been exploited to give access to kappa(1) sigma-alane complexes featuring Al-H bonds bound to [W(CO)(5)] and [Cp'Mn(CO)(2)] fragments, together with a related kappa(2) complex of [Cr(CO)(4)]. Spectroscopic, crystallographic, and quantum chemical studies are consistent with the alane ligands acting predominantly as sigma-donors, with the resulting binding energies calculated to be marginally greater than those found for related dihydrogen complexes.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available