Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 135, Issue 1, Pages 280-285Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja3089422
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Funding
- NIH COBRE [P20 RR017716]
- American Chemical Society Petroleum Research Fund
- NSF
- NIH [NSF MIR 0421224, NSF CRIF MU CHE0840401, NIH P20 RR017716]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1048367] Funding Source: National Science Foundation
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We have developed a nickel-catalyzed cross coupling of benzylic ammonium triflates with aryl boronic acids to afford diarylmethanes and diarylethanes. This reaction proceeds under mild reaction conditions and with exceptional functional group tolerance. Further, it transforms branched benzylic ammonium salts to diarylethanes with excellent chirality transfer, offering a new strategy for the synthesis of highly enantioenriched diarylethanes from readily available chiral benzylic amines.
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