Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 10, Pages 4683-4693Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja2098222
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Funding
- Landesgraduiertenstiftung Baden-Wurttemberg
- Deutsche Forschungsgemeinschaft [PE 818/4-1, SFB/TRR 88 3MET]
- Baden-Wurttemberg Stiftung
- Carl-Zeiss Stiftung
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A combination of spectroscopic and electrochemical methods-XANES, EXAFS, X-ray, H-1 NMR, EPR, Mossbauer, and cyclic voltammetry-demonstrate that the most efficient Pd catalysts for the asymmetric rearrangement of allylic trifluoroacetimidates unexpectedly possess in the activated oxidized form a Pd-III center bound to a ferrocene core which remains unchanged (Fe-II) during the oxidative activation. These are the first recognized Pd-III complexes acting as enantioselective catalysts.
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