Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 14, Pages 6128-6131Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja301989d
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- Japan Society for the Promotion of Science
- SENTAN from the Japan Science and Technology Agency
- Grants-in-Aid for Scientific Research [21245020] Funding Source: KAKEN
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Ice chromatography measurements have revealed anomalous enhancements of crown ether complexation in a liquid phase coexistent with ice. The 4 orders of magnitude enhancement was confirmed for the complexation of dibenzo-24-crown-8 in sub-pm-sized liquid inclusions formed in ice doped with <1 mM NaCl or KCl. This enhancement became less pronounced with increasing dopant concentration.
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