Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 6, Pages 3208-3214Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja210933h
Keywords
-
Categories
Funding
- National Science Foundation [CHE-0957591]
- Direct For Mathematical & Physical Scien [0957591] Funding Source: National Science Foundation
- Division Of Chemistry [0957591] Funding Source: National Science Foundation
Ask authors/readers for more resources
During attempts to produce novel two-dimensional cocrystals by coadsorbing components in a binary mixture, the formation of a metastable form was observed in analogy to the phenomenon of additive-induced polymorph formation reported in three-dimensional crystallization. Mechanistic in-sights into this phenomenon were gained through the use of scanning tunneling microscopy and several adsorbate/additive combinations. One additive plays a critical role in forming a disordered assembly through a process that is primarily kinetic whereas another additive thermodynamically stabilized an intermediate form, resulting in interrupting a phase transformation to a more stable form. These additive effects elucidate one of the potential pathways to kinetically isolate a metastable polymorph formed during cocrystallization in three-dimensional crystallization.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available