Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 49, Pages 20017-20020Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja310203c
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Funding
- Nissan Chemical Industries, Ltd.
- MEXT, Japan (WPI-I2CNER)
- MEXT, Japan (JSPS KAKENHI) [23245009]
- JSPS
- Grants-in-Aid for Scientific Research [11J03551, 23245009] Funding Source: KAKEN
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Iron(salan) complex 1 was found to catalyze the oxidative dearomatization of 1-substituted 2-naphthols with the formation of an all-carbon quaternary stereocenter in air in the presence of nitroalkanes, to afford the corresponding cyclic enones with high enantioselectivity of 88-96% ee.
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