Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 38, Pages 16040-16046Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja307431k
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Funding
- Mitsubishi Chemical Center for Advanced Materials at UCSB
- NSF SOLAR program [CHE-1035292]
- MRSEC Program of the NSF [DMR-1121053]
- NSF
- California Nanosystems Institute Graduate Research Fellowships
- DOE Office of Science for a Graduate Fellowship (DOE SCGF)
- Direct For Mathematical & Physical Scien [1035292] Funding Source: National Science Foundation
- Division Of Chemistry [1035292] Funding Source: National Science Foundation
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A novel strategy for the synthesis of fully conjugated donor acceptor block copolymers, in a single reaction step employing Stille coupling polymerization of end-functional polythiophene and AA + BB monomers, is presented. The unique donor acceptor structure of these block copolymers provides a rich self-assembly behavior, with the first example of a fully conjugated donor acceptor block copolymer having two separate crystalline domains being obtained.
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