Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 41, Pages 16955-16958Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja3076555
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Funding
- MEXT, Japan
- Asahi Glass Foundation
- JSPS
- Grants-in-Aid for Scientific Research [24750089, 11F01035] Funding Source: KAKEN
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A rhodium-catalyzed asymmetric synthesis of silicon-stereogenic dibenzooxasilines has been developed. High enantioselectivities have been achieved by employing (S,S)-Me-Duphos as the ligand through enantioselective transmetalation.
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