Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 44, Pages 18185-18188Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja3082582
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Funding
- ConvEne IGERT Program [NSF-DGE 0801627]
- U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-AC02-06CH11357]
- Center for Scientific Computing at the California NanoSystems Institute
- MRL
- NSF MRSEC [DMR-1121053]
- NSF [CNS-0960316]
- IMI Program of the National Science Foundation [DMR-0843934]
- Direct For Computer & Info Scie & Enginr
- Division Of Computer and Network Systems [960316] Funding Source: National Science Foundation
- Direct For Mathematical & Physical Scien [0843934] Funding Source: National Science Foundation
- Division Of Materials Research [0843934] Funding Source: National Science Foundation
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Substituted N-alkyldinaphthocarbazoles were synthesized using a key double Diets-Alder reaction. The angular nature of the dinaphthocarbazole system allows for increased stability of the conjugated system relative to linear analogues. The N-alkyldinaphthocarbazoles were characterized by UV-vis absorption and fluorescence spectroscopy as well as cyclic voltammetry. X-ray structure analysis based on synchrotron X-ray powder diffraction revealed that the N-dodecyl-substituted compound was oriented in an intimate herringbone packing motif, which allowed for p-type mobilities of 0.055 cm(2) V-1 s(-1) from solution-processed organic field-effect transistors.
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