Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 51, Pages 20701-20704Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja307924a
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Funding
- BMBF, Bundesministerium fur Bildung und Forschung [01RC 1006H]
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The most efficient, stable, and easy-to-synthesize non-noble metal catalyst system for the reduction of CO2 and bicarbonates is presented. In the presence of the iron(II)-fluoro-tris(2-(diphenylphosphino)phenyl)phosphino]tetrafluoroborate complex 3, the hydrogenation of bicarbonates proceeds in good yields with high catalyst productivity and activity (TON > 7500, TOF > 750). High-pressure NMR studies of the hydrogenation of carbon dioxide demonstrate that the corresponding iron-hydridodihydrogen complex 4 is crucial in the catalytic cycle.
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