Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 45, Pages 18538-18541Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja308700t
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Funding
- National Science Foundation [CHE-0957215]
- Richard T. and Hugh G. Chatham Fund for Faculty Research and Development
- UNC EFRC: Center for Solar Fuels, an Energy Frontier Research Center
- U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-SC0001011]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0957215] Funding Source: National Science Foundation
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Benzoquinone/hydroquinone redox inter conversion by the reversible Os(dmb)(3)(3+/2+) couple over an extended pH range with added acids and bases. has revealed the existence of seven discrete pathways. Application of spectrophotometric monitoring with stopped-flow mixing has been used to explore the role of PCET. The results have revealed a role for phosphoric acid and acetate as proton donor and acceptor in the concerted electron-proton transfer reduction of benzoquinone and oxidation of hydroquinone, respectively.
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