Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 35, Pages 14295-14297Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja305477a
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Funding
- Funding Program for Next Generation World-Leading Researchers (NEXT Program) [GR-003]
- Grants-in-Aid for Scientific Research [24109003] Funding Source: KAKEN
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A gold cluster, Au-41(S-Eind)(12), was synthesized by ligating the bulky arenethiol 1,1,3,3,5,5,7,7-octaethyl-s-hydrindacene-4-thiol (Eind-SH) to preformed Au clusters. Extended X-ray absorption fine structure, Xray photoelectron spectroscopy, and the fragmentation pattern in the mass spectrometry analysis indicated that formation of gold thiolate oligomers at the interface was suppressed, in sharp contrast to conventional thiolate-protected Au clusters.
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