Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 29, Pages 11852-11855Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja303552p
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Funding
- Max Planck Society
- Sino-German center [GZ 725]
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A facile, template-free synthetic route is reported toward poly(ionic liquid) complexes (PILCs) which for the first time exhibit stable micro-/mesoporous structure. This is accomplished via in situ ionic complexation between imidazolium-based PILs and poly(acrylic acid) in various alkaline organic solvents. The PILC can be highly loaded with copper salts and can be used as a catalytic support for effective aerobic oxidation of activated hydrocarbons under mild conditions.
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