Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 19, Pages 8014-8017Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja300888t
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Funding
- NSF [CHE0909587, CHE0840463]
- Harry and Cleio Greer Fellowship
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0909587] Funding Source: National Science Foundation
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The direct conversion of a Mn-III complex [(TBP(8)Cz)Mn-III (1)] to a Mn-V-oxo complex [(TBP(8)Cz)Mn-V(O) (2)] with O-2 and visible light is reported. Complex 1 is also shown to function as an active photocatalyst for the oxidation of PPh3 to OPPh3. Mechanistic studies indicate that the photogeneration of 2 does not involve singlet oxygen but rather likely occurs via a free-radical mechanism upon photoactivation of 1.
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