Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 19, Pages 8074-8077Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja302704m
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Funding
- University of Michigan
- NSF [CHE-0840456]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0840456] Funding Source: National Science Foundation
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Catalytic enantioselective and diastereoselective spiroketalizations with BINOL-derived chiral phosphoric acids are reported. The chiral catalyst can override the inherent preference for the formation of thermodynamic spiroketals, and highly selective formation of nonthermodynamic spiroketals could be achieved under the reaction conditions.
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