Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 135, Issue 3, Pages 967-970Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja310782k
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Funding
- US-Israel Binational Science Foundation [2010119]
- Directorate for STEM Education
- Division Of Research On Learning [2010119] Funding Source: National Science Foundation
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The first Pd-pincer complex bearing a halogen (fluorine) arm has been prepared via the base-assisted dearomatization of a phosphine-quinoline (P similar to N) ligand. This dearomatization is reversible and has been used to facilitate catalytic Sonogashira-type cross-coupling that, contrary to the typical mechanistic approach, is based on a metal-ligand cooperation mode.
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