Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 49, Pages 20021-20024Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja3102192
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Funding
- NSF [CHE-1110911, CHE-0750303, DMR-1006761, EXP-LA 0731153]
- BGSU
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1110911, 0750303] Funding Source: National Science Foundation
- Grants-in-Aid for Scientific Research [23750167] Funding Source: KAKEN
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A supramolecular assay based on two fluorescent cucurbit[n]uril probes enables the recognition and quantification of nitrosamines, including cancer-associated nitrosamines, compounds that are difficult to recognize. The cross-reactive sensor leverages weak interactions and competition among the probe, metal, and guest, yielding high information density in the signal output (variance) and enabling the recognition of structurally similar guests.
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