Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 8, Pages 3699-3702Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja3002953
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- JSPS
- Grants-in-Aid for Scientific Research [09J05248, 22685010] Funding Source: KAKEN
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Pyridine undergoes addition of pinacolborane at 50 degrees C in the presence of a rhodium catalyst, giving N-boryl-1,2-dihydropyridine in a high yield. The selective 1,2-hydroboration also takes place in the reactions of substituted pyridines. In the reaction of 3-substituted pyridines, 3-substituted N-boryl-1,2-dihydropyridines are formed regioselectively.
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