4.8 Article

Fullerene Crystals with Bimodal Pore Architectures Consisting of Macropores and Mesopores

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 135, Issue 2, Pages 586-589

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja3108752

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Funding

  1. International Center for Materials Nanoarchitectonics (WPI-MANA)
  2. National Institute for Materials Science (NIMS)

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A new class of fullerene (C-60) crystals with bimodal pore architectures consisting of macropores and mesopores was synthesized by using a liquid-liquid interfacial precipitation (LLIP) method involving an interface between isopropyl alcohol (IPA) and a saturated solution of C-60 in a mixture of benzene and carbon tetrachloride (CCl4). By varying the mixing fraction of CCl4 in benzene, the porosity and electrochemically active surface area can be flexibly controlled.

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