4.8 Article

A Luminescent Mixed-Lanthanide Metal-Organic Framework Thermometer

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 9, Pages 3979-3982

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja2108036

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Funding

  1. Welch Foundation [AX-1730]
  2. National Natural Science Foundation of China [50802084, 50928201, 50972127, 51010002]
  3. Fundamental Research Funds for the Central Universities

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A luminescent mixed lanthanide metal-organic framework approach has been realized to explore luminescent thermometers. The targeted self-referencing luminescent thermometer Eu0.0069Tb0.9931-DMBDC (DMBDC = 2, 5-dimethoxy-1, 4-benzenedicarboxylate) based on two emissions of Tb3+ at 545 nm and Eu3+ at 613 nm is not only more robust, reliable, and instantaneous but also has higher sensitivity than the parent MOF Tb-DMBDC based on one emission at a wide range from 10 to 300 K.

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