Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 37, Pages 15309-15311Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja308194w
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Funding
- National Science Foundation [CHE-0952912]
- Welch Foundation [A-1423]
- Texas AM University
- Air Force Research Laboratory Space Vehicles Directorate [AF9453-08-C-0172]
- BGSU Research Enhancement Initiative
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0952912] Funding Source: National Science Foundation
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The 9-anthryltriphenylstibonium cation, [1](+), has been synthesized and used as a sensor for the toxic fluoride anion in water. This stibonium cation complexes fluoride ions to afford the corresponding fluorostiborane 1-F. This reaction, which occurs at fluoride concentrations in the parts per million range, is accompanied by a drastic fluorescence turn-on response. It is also highly selective and can be used in plain tap water or bottled water to test fluoridation levels.
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