Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 31, Pages 12932-12935Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja3059827
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Funding
- U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-SC0006937]
- NSF [CHE-9808061, DBI-9729592, DMR-0819762]
- Funding Program for Next-Generation World-Leading Researchers (NEXT Programs) of the Japan Society for the Promotion of Science (JSPS)
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [946721] Funding Source: National Science Foundation
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The tetratopic ligand tetrathiafulvalene-tetrabenzoate (H4TTFTB) is used to synthesize Zn-2(TTFTB), a new metal-organic framework that contains columnar stacks of tetrathiafulvalene and benzoate-lined infinite one-dimensional channels. The new MOF remains porous upon desolvation and exhibits charge mobility commensurate with some of the best organic semiconductors, confirmed by flash-photolysis-time-resolved microwave conductivity measurements. Zn-2(TTFTB) represents the first example of a permanently porous MOF with high charge mobility and may inspire further exploration of the electronic properties of these materials.
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